R-Ferrite-type barium cobalt stannate, BaCo2Sn4O11

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R-Ferrite-type barium cobalt stannate, BaCo2Sn4O11

BaCo(2)Sn(4)O(11) is isotypic with R-ferrite, BaTi(2)Fe(4)O(11). The Co atoms fully occupy trigonal-bipyramidal sites () and are disordered with Sn atoms in octa-hedral sites (.2/m symmetry), as represented in the formula BaCoSn(2)(Co(0.34)Sn(0.66))(4)O(11). Ba atoms are situated in a 12-fold coordinated site ( symmetry).

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The structural transformation of substituted hexagonal ferrite powders BaFetoCoTiO~s prepared by mechanical milling, was investigated as a fimction of grinding time by means of MOssbauer spectrometry and static magnetic measurements. A spin reorientation is clearly evidenced from the temperature dependence of the hyperfine parameters and of the initial magnetic permeability on the powder mechan...

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Atomically flat ultrathin cobalt ferrite islands.

A route for fabricating structurally perfect cobalt ferrite magnetic nanostructures is demonstrated. Ultrathin islands of up to 100 μm(2) with atomically flat surfaces and free from antiphase boundaries are developed. The extremely low defect concentration leads to a robust magnetic order, even for thicknesses below 1 nm, and exceptionally large magnetic domains. This approach allows the evalua...

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Cobalt ferrite nanocrystals: out-performing magnetotactic bacteria.

Magnetotactic bacteria produce exquisitely ordered chains of uniform magnetite (Fe(3)O(4)) nanocrystals, and the use of the bacterial mms6 protein allows for the shape-selective synthesis of Fe(3)O(4) nanocrystals. Cobalt ferrite (CoFe(2)O(4)) nanoparticles, on the other hand, are not known to occur in living organisms. Here we report on the use of the recombinant mms6 protein in a templated sy...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808030572